If the amp sounds sweet, then record it. I do think though, that sometimes you have an amp totally cranked, it sounds much different than the same, at a moderate volume that sounds sweet. But, recorded, it sounds different yet.So recording volumes... how loud do you need to have the volume? I was recording my Mesa RA100 (mic'd to a 1960a with V30's). I pulled the mic back just a tad, found the right spot near the cone, and then pushed the volume to the get the tubes glowing, and recorded my track. Earlier, I had recorded the same track as I wanted to just capture a good version of the song end-to-end, and I did it at fairly lower volumes (just to capture the track, then delete it later after I recorded my final tracks). I noticed that there wasn't a big difference between the tracks with one recorded about 9 o'clock vs. the one where I cranked the amp to get the tubes glowing and the speakers moving. With master volume amps, and with the mic right up to the speakers, is there really a benefit of recording at louder volumes? I know with my Marshall 74' 1987 and my JCM800, I get the benefit of pushing the volume, but is there really any benefit of recording a loud master volume amp?
I like having my ISO box, because I can crank it to whatever sounds good & try different things & never have to worry about getting the noise in the environment.
I notice that the Kemper records at like -12db, or so & I'm thinking that, that's probably a good level to have your DAW set at, for recording.
I think mic placement & just having a sweet sound is more important than just blasting the amp & hoping for the best. If you have someone engineering, while you play & another guy w/ a headset positioning the mic, then you can do whatever, but, if you are doing it alone, a good set of headphones & an extension cord are important. Still though, it will be difficult to separate the cab & the headphone.
I find that 45º angles +/- seem to work well w/ recording the speaker. If close proximity, I like to have the mic at the edge of the dust cap (center dome) & then, tilt the mic 45º away from center, so you are getting the voice coil close, but off-axis & getting the paper cone, towards the outside on axis. I use large diaphragm condensors though.
Another thing would to be having the mic away from the cab at a distance 6" or more, & at a 45º angle, so it's 6" out & 6" to the side of the voice coil & aim it across the voice coil to the furthest rim of the dust cap. Same thing when mic'ing from a distance...
Using multiple mic's is a bit more technical though, because then you are working w/ phase...